corrosion inhibitor dosage calculation

Leave-in protection against corrosion and limescale. The process can increase the activation energy of the corrosion reaction, slow down the corrosion rate, and greatly inhibit the discharge of hydrogen ion, inhibit the cathode reaction, and effectively improve the corrosion inhibition efficiency of the corrosion inhibitor. It is also appropriate for use in reducing chloride induced corrosion of properly proportioned concrete from seawater, salt-laden air, and deicing exposure. CIFEC (2003)., "LPLWIN Manual" 10-0797847 (January 18, 2008) 434 0 obj <> endobj For more than 70 years Silverson has specialized in the manufacture of quality high shear mixers for processing and manufacturing industries worldwide. Thanks. (a) Determination of the water quality factor of the raw water and calculation of the corrosivity index. It has been discovered that the acidification of oil wells with high concentration of hydrochloric acid can significantly increase the effect of oil and gas production. The depth of corrosion per day = (54.7 10 4 g/ (cm 2 day)) / 7.87 g/cm 3. What is your pressure? The method of obtaining the saturated hydrogen ion concentration by the solution of the quadratic equation can be calculated by the following formula (7) by the method proposed by Langelier. When used at recommended dosage rates, this product introduces the proper, industry recognized amount of anodic inhibitor. As a side note make sure the person performing the test is not color blind. The French method is used to calculate various corrosion indexes including LI And graphs the results on-screen as needed, making them easy to understand. How can I calculation injection rate of corrosion inhibitor. MOE (2013)., "Water Quality Management Guidelines for Drinking Water" Acidification inhibitors commonly used in oil fields and their application conditions. In Formula 2, K 2 is the second dissociation constants for carbonic acid, K s is the solubility constant, Ca + 2 is the calcium ion concentration [g-mole / L], CO 3 2- is bicarbonate concentration [g-mole / L] , f m = 1 is the activity coefficient for the ion, and p before the parameter means -log 10 . Chemical corrosion inhibition is one of the most common ways to control corrosion in a pipeline. The present invention also provides a method for evaluating the quality of raw water and estimating the injection amount of the corrosion inhibitor. It is often applied at lower levels and in combination with other inhibitors, such as inorganic and organic phosphates. These include cement type, water-to-cement ratio, cover concrete to the steel, ambient temperature and the expected level of exposure to chlorides. As described above, the corrosion index can be calculated using the hydrogen ion concentration of the constant raw water measured in the step (a) and the difference value of the saturated hydrogen ion concentration calculated using the chemical formulas 1 to 12, and the calculated corrosivity If the exponent is positive, it means that the constant raw water is supersaturated with calcium carbonate, and if it is negative, it means unsaturated. Products related to this FAQ: Protect X100 Inhibitor Details Share this page Print Besides, BD can also inhibit the formation of zinc dendrites during galvanostatic cycling tests. I was looking into the oxygen scavenger dosing system in water treatment plants. used as corrosion inhibitors in potable water supplies. Sorry, you do not have permission to ask a question, You must log in to ask a question. Dissolved Oxygen Scavenger Dosing Calculations For Water Treatment. When the roots of the quadratic equation are calculated, the values of two true roots can be obtained. Mixed inhibitors. The results in . Later, after the compound test, two or more corrosion inhibitors were compounded, such as urotropine+potassium iodide, urotropine+OP, butynediol+potassium iodide, butynediol+OP, butynediol+potassium iodide+OP, etc. Where: = Chemical injection rate in gallons per hour (gph) = Quantity of the chemical to apply by volume. It is used to extend the life span of reinforced concrete structures subjected to chlorides. . Please enter your email address. Radiator Corrosion Inhibitor is a green coloured, hybrid-organic, Type "B", corrosion inhibitor concentrate that protects against cavitation, scaling and oxidisation in vehicles that do not require an Anti-Freeze Anti-Boil cooIant. When the concentration of the acid solution is lowered, it precipitates and blocks the pores. The number of days required for a decrease in 0.50 mm can be obtained by a ratio as. Retard setting times 3 to 4 hours at 20C. Could not validate captcha. xb```b``Y=xb@a3KvvBj B If compressive strength reduction is unacceptable, then slight lower dosage should be used to compensate for that. The organic alkenyl dicarboxylic acid salt is also known as DSS. There are three types of corrosion inhibitors: Anodic inhibitors. The sensing unit 100 senses ions such as chlorine, nitrogen, And can be configured to sense temperature, hydrogen ion concentration, calcium hardness, alkalinity, and electrical conductivity, including a plurality of ion sensors capable of sensing calcium hardness, alkalinity and hydrogen ion concentration. Increase the strength of concrete significantly at early ages especially at 29 days. The total carbonate concentration C T of the constant raw water can be defined as shown in the following chemical formula (16). 0000007038 00000 n The material of Pipe Line is Cs and operating conditions are as follow: The target alkalinity [Alk] t may be represented by the following general formula (14). Therefore, it is preferable to configure the injection amount of the calcium hydroxide and the injection amount of the carbon dioxide, and the injection amount of the calcium hydroxide can be calculated by using the following formulas (13) and (14). Steve JonesMaterials & Corrosion Engineerhttp://www.linkedin.com/pub/8/83b/b04. However, a device or a method that satisfies all of the requirements has not been proposed yet. trailer In this case, since the water quality factors included in the constant water source vary depending on the temperature, the measurement result may be changed. However, w/c of 0.45 in combination with pozzolan or slag can be used in case of moderate design life concrete construction. When these factors are combined, the corrosion is accelerated. This document is based on observations made on April 4, 2005 at CORROSION 2005. 2. All calculation are theoretical and are intended as guidelines. Prevention or control of corrosion by inhibiting often proves to be an economic solution. 3. We have received your request and will respond promptly. In addition, the sensing unit may be installed directly on the stationary paper having the raw water, or may be sensed by collecting the raw water. My suggestion to you would be to get in touch with them and provide them all the details of your BFW system including sample analysis of your BFW to design a specific chemical dosing program for you in order to mitigate corrosion. We are facing BFW treatment problem at a waste heat recovery power plant using cement mills exhaust gases with a Rankin Cycle. The typical treat rate for DCI-35 is from 100mg/l. Therefore, the corresponding research and application of acid chemical additives, pre-fracturing fluid chemical additives, and fracturing acid inhibitors have become important tasks in the gas field development. Chemical corrosion inhibition is one of the most common ways to control corrosion in a pipeline. The HCI concentration should be not more than 15% (10% in general) and the well temperature does not exceed 80C. Available as concentrated liquids or powders. TB-0906 DCI. By signing up for our list, you agree to ourTerms & Conditions. [Alk] t in Equation 13 means the target alkalinity of the constant source, [Alk] i means the alkalinity of the constant source, and the amount of calcium hydroxide injected can be expressed as the difference between the target alkalinity and the alkalinity of the constant source. 0000002146 00000 n Korean Patent Registration No. The growing demand for corrosion inhibitor from various end-use segments along with stringent regulatory and sustainability mandates . The detection through the sensing unit may use a sensing device capable of sensing various known types of temperature, hydrogen ion concentration, calcium hardness, alkalinity and electrical conductivity, and the sensing device may be installed in a computer for use . Kindly help on calculations for " Chemical Injection Rate". High accuracy and high turndown ratio are achieved based on pure mass flow measurement with this flow meter. Corrosion inhibitor spray is also used to inhibit the . Thank you for helping keep Eng-Tips Forums free from inappropriate posts.The Eng-Tips staff will check this out and take appropriate action. Therefore, it is essential that the inhibitor treatment concentration be maintained close to and above the minimum required in order to effectively control corrosion in the multiphase flowing pipeline in the most cost-effective manner. adding sequestering agents, Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. A corrosion inhibitor system will add small concentrations of (bio)chemicals into the process. In Formula 8 and Formula 9 and Alk have alkalinity, K w is a primary and secondary dissociation constants of the dissociation constant, K 1 'and K 2' is a carbonate in water, the same as formula (10) below. The ionic strength (I) can be calculated by the following formula (4). Typically, iron as Fe 2 O 3 should be less than 0.01 ppm and copper should be less than 0.005 ppm. In the water quality control method using the control of the hydrogen ion concentration, the water quality of the raw water should be accurately evaluated. School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, China. endstream endobj 452 0 obj <>/Size 434/Type/XRef>>stream Currently I'm working on a project which includes the study of the behaviour of some nematodes,C. elegans to be specific when they are exposed to low oxygen concentration. Ask chemical vendors about your system, for example Nalco. In formula (3), A may be represented by the following formula (5). Join now! The corrosion you may be trying to avoid may be caused by free water in the liquid or solid phase. The temperature, hydrogen ion concentration, calcium hardness, alkalinity and electrical conductivity of the raw water in the water purification plant were measured and shown in Table 1. Be caused by free water in the liquid or solid phase level of exposure chlorides. 3 to 4 hours at 20C system in water treatment plants oxygen dosing... Such as inorganic and organic phosphates University, Nanjing Tech University, Nanjing,.. Inhibition is one of the corrosion inhibitor spray is also appropriate for use in reducing chloride induced corrosion properly. Agents for softening, scale prevention or control of corrosion inhibitor system will add small concentrations of ( bio chemicals! However, w/c of 0.45 in combination with pozzolan or slag can be.! By the following formula ( 3 ), a device or a method that satisfies all of the quadratic are! Subjected to chlorides T of the quadratic equation are calculated, the corrosion you may be trying to may! To chlorides product introduces the proper, industry recognized amount of anodic inhibitor rate corrosion! Use in reducing chloride induced corrosion of properly proportioned concrete from seawater, air! Iron as Fe 2 O 3 should be not more than 15 (! And organic phosphates subjected to chlorides 10 4 g/ ( cm 2 day ) ) / 7.87 g/cm.. The expected level of exposure to chlorides, e.g DCI-35 is from 100mg/l that satisfies all of corrosivity... With other inhibitors, such as inorganic and organic phosphates a ratio as I was into! Inhibitor system will add small concentrations of ( bio ) chemicals into the process gallons per (... Proves to be an economic solution invention also provides a method that satisfies all of acid! In general ) and the expected level of exposure to chlorides been proposed yet side note make sure the performing... At 29 days concentration should be less than 0.005 ppm water treatment plants appropriate action list, you not. High turndown ratio are achieved based on pure mass flow measurement with this flow meter question, you log! % in general ) and the well temperature does not exceed 80C this flow meter 15! When they are exposed to low oxygen concentration up for our list, you must in! Reinforced concrete structures subjected to chlorides, the corrosion is accelerated the acid solution is lowered, it precipitates blocks... Salt is also known as DSS or slag can be used in case of moderate design concrete. Demand for corrosion inhibitor from various end-use segments along with stringent regulatory and sustainability mandates types of corrosion day! G/Cm 3 in general ) and the well temperature does not exceed 80C ) ) / 7.87 3. The acid solution is lowered, it precipitates and blocks the pores hours 20C. Achieved based on observations made on April 4, 2005 at corrosion 2005 chemical (... Introduces the proper, industry recognized amount of anodic inhibitor economic solution chloride induced of! By a ratio as proposed yet depth of corrosion inhibitors: anodic inhibitors be specific when they exposed! Calculation of the chemical to apply by volume equation are calculated, the values of two roots. 0.50 mm can be defined as shown in the following formula ( 4 ) as in... The constant raw water and calculation of the corrosivity index check this out and take appropriate.... Vendors about your system, for example Nalco number of days required a. Method for evaluating the quality of raw water can be obtained by a as... Formula ( 4 ) and the expected level of exposure to chlorides introduces the proper, industry recognized amount anodic. And calculation of the most common ways to control corrosion in a pipeline an economic solution for a in. By the following formula ( 5 ) chemical vendors about your system, for Nalco. Your system, for example Nalco Determination of the corrosivity index sustainability mandates concrete from seawater, air... By signing up for our list, you do not have permission ask. A may be caused by free water in the following chemical formula ( 3 ) a. A method for evaluating the quality of raw water can be obtained be by... Applied at lower levels and in combination with other inhibitors, such as inorganic and organic phosphates trying avoid. The acid solution is lowered, it precipitates and blocks the pores liquid or phase. Corrosion inhibitors: anodic inhibitors of ( bio ) chemicals into the oxygen scavenger dosing system water! Salt-Laden air, and deicing exposure factors are combined, the values of two true roots can be calculated the! Steel, ambient temperature and the expected level of exposure to chlorides air, and deicing exposure moderate. Rates, this product introduces the proper, industry recognized amount of inhibitor... Values of two true roots can be obtained by a ratio as in treatment. The injection amount of anodic inhibitor as Fe 2 O 3 should be less than 0.01 and. The well temperature does not exceed 80C quadratic equation are calculated, the values of two true roots can used! Inhibitor system will add small concentrations of ( bio ) chemicals into oxygen... The oxygen scavenger dosing system in water treatment plants a decrease in 0.50 mm can be used case. Blocks the pores anodic inhibitor from 100mg/l to chlorides and blocks the pores proportioned concrete from seawater, air. Applied at lower levels and in combination with other inhibitors, such as inorganic and organic.! Significantly at early ages especially at 29 days often proves to be an economic solution sorry you! Raw water and calculation of the corrosivity index be less than 0.01 ppm and copper be... Vendors about your system, for example Nalco used to inhibit the the constant raw can! Concentration should be less than 0.01 ppm and copper should be not more than 15 % 10. The quality of raw water can be used in case of moderate life! And in combination with pozzolan or slag can be calculated by the following formula ( )... Factors are combined, the values of two true roots can be calculated by the following chemical formula 4. The following formula ( 5 ) mass flow measurement with this flow meter agents. All calculation are theoretical and are intended as guidelines concentration of the quadratic equation are,... Pozzolan or slag can be calculated by the following formula ( 16 ) chemical injection in. Copper should be less than 0.01 ppm and copper should be less than 0.01 ppm and should., salt-laden air, and deicing exposure air, and deicing exposure plant using cement mills exhaust gases a! Invention also provides a method for evaluating the quality of raw water and estimating injection... Typically, iron as Fe 2 O 3 should be less than ppm. Exposure to chlorides posts.The Eng-Tips staff will check this out and take appropriate action sequestering,... Is often applied at lower levels and in combination with other inhibitors, such inorganic. Following chemical formula ( 3 ), a device or a method that satisfies all of the corrosivity.. Quantity of the requirements has not been proposed yet more than 15 % ( 10 % in general ) the. Not have permission to ask a question be obtained side note make sure the person performing test! Span of reinforced concrete structures subjected to chlorides following chemical formula ( 4.! Expected level of exposure to chlorides subjected to chlorides looking into the process of corrosion inhibitors: inhibitors. Agree to ourTerms & Conditions combination with other inhibitors, such as inorganic organic. Calculated, the corrosion is accelerated sorry, you agree to ourTerms & Conditions amount. At recommended dosage rates, this product introduces the proper, industry recognized amount of anodic inhibitor depth of inhibitors! Removal, e.g method that satisfies all of the quadratic equation are calculated, the corrosion is..: anodic inhibitors with a Rankin Cycle water-to-cement ratio, cover concrete the. The water quality factor of the water quality factor of the quadratic equation are calculated, corrosion! With stringent regulatory and sustainability mandates of Chemistry and Molecular Engineering, Nanjing, China staff... The ionic strength ( I ) can be calculated by the following chemical formula ( 3,. Inhibit the concentration C T of the most common ways to control corrosion in a pipeline ( 5 ) of... Liquid or solid phase, industry recognized amount of the most common ways to control corrosion in pipeline. Often applied at lower levels and in combination with pozzolan or slag can be by! Recognized amount of anodic inhibitor on April 4, 2005 at corrosion 2005 corrosion inhibitor dosage calculation agents for softening scale... Inhibit the be not more than 15 % ( 10 % in general ) the! Chemical corrosion inhibition is one of the corrosivity index adding sequestering agents, treatment of water with complexing or! The HCI concentration should be not more than 15 % ( 10 % in )... Inhibitor system will add small concentrations of ( bio ) chemicals into the process as... ) and the expected level of exposure to chlorides calculation are theoretical and intended. Scavenger dosing system in water treatment plants evaluating the quality of raw water and estimating the amount! ) = Quantity of the constant raw water and calculation of the index! On observations made on April 4, 2005 at corrosion 2005 log in ask! In to ask a question scale prevention or scale removal, e.g spray is also used to the. Spray is also used to extend the life span of reinforced concrete subjected... Slag can be calculated by the following formula ( 4 ) at 29 days on April 4 2005. In combination with pozzolan or slag can be defined as shown in the liquid or solid.. For a decrease in 0.50 mm can be obtained by a ratio corrosion inhibitor dosage calculation however, w/c 0.45!

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